全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
化学进展  2014 

用于锕系分离和三价镧系/锕系分离的水溶性配体

DOI: 10.7536/PC140531, PP. 1655-1664

Keywords: 锕系,镧系,水溶性配体,配合物

Full-Text   Cite this paper   Add to My Lib

Abstract:

三价镧系(Lns(Ⅲ))与锕系(Ans(Ⅲ))分离是核工业高放废液处理过程中十分重要的环节。由于两者物理化学性质极为相近,分离难度很大,Lns(Ⅲ)与Ans(Ⅲ)的分离被公认为是最具挑战性的课题之一,迄今尚未得到满意解决。为实现两者的分离,技术上有两条途径可供选择一是开发对Ans(Ⅲ)有高选择性的脂溶性萃取剂;二是开发对Ans(Ⅲ)有良好配位性质的水溶性配体。近年来,这两方面研究都已取得了较大进展。就后者而言,发现一些水溶性酰胺和吡啶衍生物、氨羧络合剂等配体对Ans(Ⅲ)有很好的选择性。它们已作为Ans(Ⅲ)的反萃剂或掩蔽剂用于Lns(Ⅲ)与Ans(Ⅲ)的分离。为此,本文就这些水溶性配体在对Lns(Ⅲ)和Ans(Ⅲ)萃取的影响、配合物组成与结构以及配位反应热力学性质等研究方面取得的进展进行综述,并对进一步的研究工作提出了一些建议。

References

[1]  Narbutt J, Krejzler J. Radiochim. Acta, 2008, 96: 219.
[2]  Lewis F W, Harwood L M, Hudson M J, Drew M G B, Desreux J F, Vidick G, Bouslimani N, Modolo G, Wilden A, Sypula M, Vu T H, Simonin J P. J. Am. Chem. Soc., 2011, 133: 13093.
[3]  陈靖(Chen J), 王芳(Wang F), 何喜红(He X H), 盘登芳(Pan D F). 化学进展(Progress in Chemistry), 2011, 23(7): 1338.
[4]  Sasaki Y, Sugo Y, Kitatsuji Y, Kirishima A, Kimura T, Choppin G R. Anal. Sci., 2007, 23: 727.
[5]  Sasaki Y, Suzuki H, Sugo Y, Kimura T, Chopping G R. Chem. Lett., 2006, 35: 256.
[6]  Wei M, Feng X G, Chen J. Sep. Sci. Technol., 2013, 48: 741.
[7]  Suneesh A S, Venkatesan K A, Syamala K V, Antony M P, Vasudeva Rao P R. Radiochim. Acta, 2012, 100: 425.
[8]  Zhang P, Wang H R, Wang J C, Chen J. J. Radioanal. Nucl. Chem., 2007, 273: 65.
[9]  Chen J, Wang J C, Duan W H. Proceedings of the International Solvent Extraction Conference. Tucson, 2008. 611.
[10]  Wei M, Liu X G, Chen J. J. Radioanal. Nucl. Chem., 2012, 291: 717.
[11]  Sasaki Y, Tsubata Y, Kitatsuji Y, Morita Y. Chem. Lett., 2013, 42: 91.
[12]  Nilsson M, Nash K L. Solvent Extr. Ion Exch., 2007, 25: 665.
[13]  Braley J C, Grimes T S, Nash K L. Ind. Eng. Chem. Res., 2012, 51: 629.
[14]  Fermvik A, Ekberg C, Englund S, Foreman M R S J, Modolo G, Retegan T, Skarnemark G. Radiochim. Acta, 2009, 97: 319.
[15]  Trumm S, Panak P J, Geist A, Fangh?nel T. Eur. J. Inorg. Chem., 2010, 19: 3022.
[16]  Steppert M, Walther C, Geist A, Fangh?nel T. New J. Chem., 2009, 33: 2437.
[17]  Sasaki Y, Tsubata Y, Kitatsuji Y, Sugo Y, Shirasu N, Morita Y. Procedia Chemistry, 2012, 7: 380.
[18]  Croff A C, Blomeke J O. Actinide Partitioning-Ttransmutation Program, Final Report, ORNL 5566, 1980.
[19]  Michael J. Advanced Extraction Methods for Actinide/Lanthanide Separations, Nuclear Energy Research Initiative (NERI) Final Report, Grant No. DE-FG07-02SF22614 SF 269A, Project Number 02-098, 2005.
[20]  Chopping G R. J. Less-Commom Metals, 1983, 93: 323.
[21]  Zhu Y J. Radiochim. Acta, 1995, 68: 95.
[22]  Zhu Y J, Chen J, Jiao R Z. Solvent Extr. Ion. Exch., 1996, 14: 61.
[23]  Hill C, Guilaneux D, Berthon L, Madic C. J. Nucl. Sci. Technol., 2002, S3: 309.
[24]  Drew M G B, Foreman M R S J, Hill C, Hudson M J, Madic C. Inorg. Chem. Commun., 2005, 8: 239.
[25]  盘登芳(Pan D F), 叶钢(Ye G), 王芳(Wang F), 陈靖(Chen J). 化学进展(Progress in Chemistry), 2012, 24(11): 2167.
[26]  Lewis F W, Hudson M J, Harwood L M. Synlett, 2011, 18: 2609.
[27]  Ekberg C, Fermvik A, Retegan T, Skarnemark G, Foreman M R S, Hudson M J, Englund S, Nilsson M. Radiochim. Acta, 2008, 96: 225.
[28]  Kolarik Z. Chem. Rev., 2008, 108: 4208.
[29]  Sasaki Y, Sugo Y, Suzuki S, Tachimori S. Solvent Extr. Ion Exch., 2001, 19: 91.
[30]  Sasaki Y, Tachimori S. Solvent Extr. Ion Exch., 2002, 20: 21.
[31]  Ansari S A, Pathak P N, Manchanda V K, Husain M, Prasad A K, Parmar V S. Solvent Extr. Ion Exch., 2005, 23: 463.
[32]  Zhang P, Chen J, Tian G X. CN 1203489 B, 2005.
[33]  Wei M, He Q G, Feng X G, Chen J. J. Radioanal. Nucl. Chem., 2012, 293: 689.
[34]  Tian G X, Rao L F, Teat S J, Liu G K. Chem. Eur. J., 2009, 15: 4172.
[35]  Sasaki Y, Morita Y, Kitatsuji Y, Kimura T. Chem. Lett., 2010, 39: 898.
[36]  Charbonnel M C, Berthon C, Berthon L, Boubals N, Burdet F, Duchesne M T, Guilbaud P, Mabille N, Petit S, Zorz N. Procedia Chemistry, 2012, 7: 20.
[37]  Bollesteros M J, Calor J N, Costenoble S, Montuir M, Pacary V, Sorel C, Burdet F, Espinoux D, Hérès X, Eysseric C. Procedia Chemistry, 2012, 7: 178.
[38]  Poinssot C, Rostaing C, Baron P, Warin D, Boullis B. Procedia Chemistry, 2012, 7: 358.
[39]  Iqbal M, Huskens J, Sypula M, Modolo G, Verboom W. New J. Chem., 2011, 35: 2591.
[40]  Shimojo K, Naganawa H, Noro J, Kubota F, Goto M. Anal. Sci., 2007, 23: 1427.
[41]  Tachimori S, Sato A, Nakamura H. J. Nucl. Sci. Technol., 1979, 16: 434.
[42]  Thakur P, Conca J L, Dodge C J, Francis A J, Choppin G R. Radiochim. Acta, 2013, 101: 221.
[43]  Heitzmann M, Bravard F, Gateau C, Boublas N, Berthon C, Pécaut J, Charbonnel M C, Delangle P. Inorg. Chem., 2009, 48: 246.
[44]  Heitzmann M, Gateau C, Chareyre L, Miguirditchian M, Charbonnel M C, Delangle P. New J. Chem., 2010, 34: 108.
[45]  Hudson M J, Boucher C E, Braekers D, Desreux J F, Drew M G B, Foreman M R S J, Harwood L M, Madic C, Marken F, Youngs T G A. New J. Chem., 2006, 30: 1171.
[46]  Kolarik Z, Müllich U, Gassner F. Solvent Extr. Ion Exch., 1999, 17: 1155.
[47]  Trumm S, Geist A, Panak P J, Fangh?nel T. Solvent Extr. Ion Exch., 2011, 29: 213.
[48]  Geist A, Hill C, Modolo G, Foreman M R S J, Weigl M, Gompper K, Hudson M J. Solvent Extr. Ion Exch., 2006, 24: 463.
[49]  Magnusson D, Christiansen B, Malmbeck R, Glatz J P. Radiochim. Acta, 2009, 97: 497.
[50]  Trumm S, Lieser G, Foreman M R S J, Panak P J, Geist A, Fangh?nel T. Dalton Trans., 2010, 39: 923.
[51]  Traister G L, Schilt A A. Anal. Chem., 1976, 48: 1216.
[52]  Müllich U, Geist A, Zevaco T. EP 2377861 A1, 2011.
[53]  Geist A, Müllich U, Magnusson D, Kaden P, Modolo G, Wilden A, Zevaco T. Solvent Extr. Ion Exch., 2012, 30: 433.
[54]  Magnusson D, Geist A, Malmbeck R, Modolo G, Wilden A. Procedia Chemistry, 2012, 7: 245.
[55]  Wilden A, Modolo G, Sypula M, Geist A, Magnusson D. Procedia Chemistry, 2012, 7: 418.
[56]  Ruff C M, Müllich U, Geist A, Panak P J. Dalton Trans., 2012, 41: 14594.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133