OALib Journal期刊
离子掺杂氧化锌光催化纳米功能材料的制备及其应用
DOI: 10.7536/PC140452
Keywords: 氧化锌 ,离子掺杂 ,光催化 ,催化机理 ,光降解 ,抗菌性 ,制氢
Abstract:
氧化锌是一种氧化还原电位高、激子结合能大（~60meV）、物理和化学稳定性较好、廉价且无毒的半导体光催化剂。本文综述了掺杂氧化锌光催化剂的掺杂离子类型、制备方法、光催化效果及其作用机理。掺杂氧化锌的离子类型主要包括非金属离子单掺杂、金属离子（包括过渡金属离子和稀土金属离子）单掺杂和双离子共掺杂。离子掺杂后可在氧化锌晶格中引入更多的氧空穴或缺陷，为光致氧化反应提供更多的活性位点；或者引入杂质能级，扩大光吸收范围，增强可见光吸收能力。同时，掺杂的离子也可作为电子捕获中心，阻止光生电子-空穴对的复合，从而提高氧化锌光催化剂的性能。此外，文中还对掺杂氧化锌光催化剂在有机污染物降解、抗菌和光催化制氢等方面的应用进行了系统概述，并对其发展趋势作了展望。
References
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