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化学进展  2015 

基于外壁作用的瓜环基超分子配位聚合物

DOI: 10.7536/PC141036, PP. 625-632

Keywords: 瓜环外壁作用,结构导向,金属-瓜环配位,配位聚合物,功能性质

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Abstract:

利用瓜环外壁的结构导向作用设计并构筑瓜环-金属离子超分子配位聚合物可能成为瓜环配位化学研究的一个新方向。根据瓜环外壁作用类型,研究内容包括1)瓜环外壁取代烷基推电子效应对瓜环基超分子配位聚合物形成的促进作用;2)瓜环外壁与化合物芳环的相互作用对瓜环基超分子配位聚合物形成的促进作用;3)瓜环外壁与无机阴离子的相互作用对瓜环基超分子配位聚合物形成的促进作用;4)瓜环外壁取代羟基的配位作用对瓜环基超分子配位聚合物形成的促进作用。这些瓜环基超分子配位聚合物可能具有吸附捕集、分离提纯和分析等功能性质。

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