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化学进展  2006 

介观化学体系中的动力学尺度效应*

, PP. 142-158

Keywords: 介观化学,非线性化学动力学,内涨落,尺度效应

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Abstract:

以生命和表面催化体系为对象,研究了介观化学体系中内涨落对体系非线性动力学行为的调控作用。内涨落可以诱导随机振荡,其强度在体系处于最佳尺度时会出现一个甚至多个极大值,并且在耦合体系中会得到进一步增强,表现为尺度共振效应、尺度选择效应和双重尺度效应,揭示了介观化学体系中尺度效应的新机制。

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