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化学进展  2007 

功能化MCM-41在有机合成中的应用

, PP. 510-519

Keywords: MCM-41,固相化,氧化,还原,烷基化,氢甲酰化,Heck,环丙烷化

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Abstract:

介孔分子筛MCM-41具有较高的比表面和规整的结构以及表面带有羟基，因此可对MCM-41进行官能团化，从而实现均相催化剂在MCM-41中的组装，达到均相催化剂多相化的目的。本文介绍了最近几年以MCM-41为主体，组装均相配合物得到固相化催化剂在氧化、还原、烷基化、氢甲酰化、Heck、环丙烷化等反应中的应用。

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