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OALib Journal期刊
ISSN: 2333-9721
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三亚甲基环碳酸酯及2,2-二甲基三亚甲基环碳酸酯开环均聚合*
, PP. 959-972
Keywords: 三亚甲基环碳酸酯,2,2-二甲基三亚甲基环碳酸酯,开环聚合,生物降解脂肪族聚碳酸酯
Abstract:
生物降解聚合物聚三亚甲基环碳酸酯（PTMC）及聚2,2-二甲基三亚甲基环碳酸酯（PDTC）在药物控释载体及其它生物医学技术领域有着良好的应用前景。与脂肪族聚酯不同，PTMC、PDTC降解时，不会产生有害的酸性化合物。PTMC、PDTC主要由三亚甲基环碳酸酯（TMC）及2,2-二甲基三亚甲基环碳酸酯（DTC）开环均聚合制备。本文总结了催化TMC、DTC开环均聚合的不同催化剂及其聚合机理，综述了近年来国内外在TMC、DTC均聚合催化剂开发上的研究进展，并对生物相容性催化剂如稀土催化剂、Ca、Mg、Zn、Fe催化剂以及酶催化剂催化TMC、DTC开环聚合的优缺点进行了比较。
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