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化学进展 2007

纳米纤维素的制备*

, PP. 1568-1575

叶代勇

Keywords: 纳米纤维素,制备,纤维素晶须,纤维素晶体

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Abstract:

在纳米尺寸范围操控纤维素分子及其超分子聚集体，结构设计并组装出稳定的多重花样，由此创制出具有优异功能的新纳米精细化工品、新纳米材料，是纤维素科学的前沿领域和热点。为了研究当前制备纳米纤维素的现状和发展方向，简述了纳米纤维素化学基础，介绍了三类纳米纤维素纳米纤维素晶体（晶须）、纳米纤维素复合物和纳米纤维素纤维，重点综述了纳米纤维素的五种制备方法化学法制备纳米纤维素晶体和晶须、生物法制备细菌纤维素、物理法制备微纤化纳米纤维素、人工合成纳米纤维素和静电纺丝制备纤维素纤维，讨论了各种制备方法的优点和缺点，指出开展纳米纤维素超分子的可控结构设计、立体与位向选择性控制与制备、分子识别与位点识别等自组装过程机理、多尺度结构效应的形成机理等基础理论性研究是主要研究基础，新型的、绿色、低能耗、快速、高效的制备方法是纳米纤维素制备方法的发展方向。

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