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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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具有聚集诱导发光性质的化合物*
, PP. 673-678
Keywords: 聚集诱导发光,聚集诱导发光增强,结晶诱导发光增强现象
Abstract:
具有聚集诱导发光（AIE）性质的有机化合物能够在聚集或固态条件下，通过改变分子组成、扭曲构象、刚性结构、堆积形态等调节荧光发射强度和波长，使其在OLED、化学/生物传感器等领域具有广阔应用前景。本文介绍了到目前有关AIE的研究进展。侧重总结了silole型、取代乙烯型（主要包括亚甲基环戊二烯型和DPDSB型）、腈取代二苯乙烯型、吡喃型、联苯型等小分子化合物和少数高分子的结构与AIE性质之间的关系，以及为解释AIE现象所提出的限制分子内的转动、避免非辐射去活、构象扭曲避免形成excimer、J－聚集态以及形成分子间的C-H/π键等理论。
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