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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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手性磷酸催化剂在不对称合成中的应用
, PP. 1534-1543
Keywords: 手性磷酸,亚胺,不对称催化
Abstract:
手性磷酸是2004年报道的一类具有新型结构的强酸性Bronsted酸催化剂，近几年来的研究取得了很大的进展，已经成为有机小分子催化剂的一个重要分支。手性磷酸在催化一系列亚胺的加成和还原反应比如Mannich、亚胺的氢转移、亚胺的膦酰化、Pictet-Spengler、Strecker、aza-Diels-Alder、Friedel-Craft和α-重氮酯的烷基化等反应时都表现出了非常好的催化活性和立体选择性。本文主要综述了手性磷酸催化剂应用于亚胺相关反应的研究进展。
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