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OALib Journal期刊
ISSN: 2333-9721
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原子转移自由基聚合引发体系的最新研究进展
, PP. 1726-1732
Keywords: 原子转移自由基聚合,引发-活化-失活过程,金属催化体系
Abstract:
本文介绍了关于原子转移自由基聚合（ATRP）引发-活化-失活过程的最新研究情况，包括RATRP、SR&NIATRP、AGETATRP、ARGETATRP以及ICARATRP等新型ATRP引发体系。这些新型ATRP体系逐渐克服了通常ATRP体系的局限性，尤其是后两种体系仅需微量（1～50ppm）价态稳定的过渡金属络合物调控聚合，大大简化了ATRP方法的工业化生产程序；本文同时介绍了杂化及双金属ATRP催化体系，这两种新型催化体系具有较高的催化活性和对聚合反应的调控能力，而且通过简单地过滤或沉降就可从聚合产物当中脱除。
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