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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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N-杂环卡宾及其金属络合物的合成*
, PP. 1229-1240
Keywords: N-杂环卡宾,金属-N-杂环卡宾络合物,咪唑盐,合成
Abstract:
由于其强给电子能力、结构易修饰性和拓扑学特性，N-杂环卡宾成为继有机膦配体之后又一类重要的配体。其金属络合物在均相及不对称催化领域的催化性能是近期研究的热点，已有许多成功的结果。本文综述了近年来N-杂环卡宾及其金属络合物以及N-杂环卡宾的重要前体咪唑盐的合成方法。金属-N-杂环卡宾络合物的合成方法包括(a)游离卡宾与金属化合物直接络合；(b)咪唑盐与金属化合物在强碱作用下络合；(c)利用Ag-NHC通过卡宾配体转移方法制备新的金属络合物。关于N-杂环卡宾前体的合成途径主要有(a)乙二醛、伯胺和多聚甲醛的缩合反应；(b)卤代烷与咪唑及其取代咪唑的烷基化反应；(c)原甲酸酯与1,2-二胺的成环反应；(d)肼或酰胺与酸酐的环化反应；(e)用Na/K对环硫脲化合物的还原反应。
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