|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
超分子模糊识别
, PP. 2095-2102
Keywords: 纳米胶囊,超分子化学,分离,模糊识别,分子识别
Abstract:
在超分子主-客体识别系统中,由专一作用如多重氢键、拓扑捕捉、金属-配体驱动的识别虽然具有高选择性,但要求主体具有严格的尺寸、形状和电子环境;同时识别通常限于那些具有拓扑特征和电子特征的分子,这类识别机制称为静态识别。另一方面,由超支化聚合物衍生的核-壳两亲大分子(CAM),方便易得且有广泛的客体亲合性,但客体选择性通常较低。近年的研究表明,CAM的核经过合适的电子性质改性后,竞争客体分子间的差异可被放大,从而实现高选择性包裹与分离,而CAM最大的特点是核内有大量随机分布的官能团,从而可以进行各种精细的改性。这一由复杂系统的非线性特征导致的识别不需要专一作用的推动,适合于复杂分子的识别,被称为超分子模糊识别。实验表明,超分子模糊识别主体可以用于各种离子客体的高效分离,还可以识别拓扑特征和电子特征非常相似的分子。本文就超分子模糊识别的机制、特点以及应用作了综述。
| [1] | Zadeh L A. IEEE Trans. Systems Man Cybernetics, 1973, 3: 28-44
|
| [2] | Shinkai S, Ikeda M, Sugasaki A, Takeuchi M. Acc. Chem. Res., 2001, 34: 494-503
|
| [3] | Pranata J, Wierschke S G, Jorgenson W L. J. Am. Chem. Soc., 1991, 113: 2810-2819
|
| [4] | Angerer L, Davidson N, Murphy W, Lynch D, Attardi G. Cell, 1976, 9: 81-90
|
| [5] | Chang S K, Hamilton D A. J. Am. Chem. Soc., 1988, 110: 1318-1319
|
| [6] | Pedersen C J. J. Am. Chem. Soc., 1967, 89: 2495-2496
|
| [7] | Chen Y, Shen Z, Pastor-Perez L, Frey H, Stiriba S E. Macromolecules, 2005, 38: 227-229
|
| [8] | Liu H J, Chen Y, Zhu D D, Shen Z, Stiriba S E. React. Funct. Polym., 2007, 67: 383-395
|
| [9] | Kitajyo Y, Nawa Y, Tamaki M, Tani H, Takahashi K, Kaga H, Satoh T, Kakuchi T. Polymer, 2007, 48: 4683-4690
|
| [10] | Wan D C, Pu H T, Jin M. Macromolecules, 2010, 43: 3809-3816
|
| [11] | Wan D C, Pu H T, Cai X Y. Macromolecules, 2008, 41: 7787-7789
|
| [12] | Wan D C, Yuan J J, Pu H T. Macromolecules, 2009, 42: 1533-1540
|
| [13] | Wan D C, Pu H T, Jin M. Macromolecules, 2009, 42: 6448-6456
|
| [14] | Wan D C, Jin M, Pu H T, Pan H Y, Chang Z H. React. Funct. Polym., 2010, 70: 916-922
|
| [15] | Wan D C, Pu H T, Jin M, Wang G W, Huang J L. J. Polym. Sci., Part A: Polym. Chem., 2011, 49: 2373-2381
|
| [16] | Buhleier E, Wehner W, Vogtle F. Synthesis, 1978, 2: 155-158
|
| [17] | Maciejewski M. J. Macromol. Sci. Chem., 1982, 17A: 689-702
|
| [18] | Jansen J F G A, Meijer E W. J. Am. Chem. Soc., 1995, 117: 4417-4418
|
| [19] | Tomoyose Y T, Jiang D L, Jin R H, Aida T, Yamashita T, Horie K, Yashima E, Okamoto Y. Macromolecules, 1996, 29: 5236-5238
|
| [20] | Baars M W P L, Froehling P E, Meijer E W. Chem. Commun., 1997, 1959-1960
|
| [21] | Balzani V, Ceroni P, Gestermann S, Gorka M, Kauffmann C, Vogtle F. Tetrahedron, 2002, 58: 629-637
|
| [22] | Jorgenson W L, Pranata J. J. Am. Chem. Soc., 1990, 112: 2008-2010
|
| [23] | Li Z, Ding J, Robertson G, Day M, Tao Y. Tetrahedron Lett., 2005, 46: 6499-6502
|
| [24] | Fan E, van Arman S A, Kincaid S, Hamilton A D. J. Am. Chem. Soc., 1993, 115: 369-370
|
| [25] | Gale P A, Sessler J L, Kraal V, Lynch V. J. Am. Chem. Soc., 1996, 118: 5140-5141
|
| [26] | Gao C, Yan D Y. Prog. Polym. Sci., 2004, 29: 183-275
|
| [27] | Kramer M, Kopagzynska M, Krause S, Haag R. J. Polym. Sci. Part A: Polym. Chem., 2007, 45: 2287-2303
|
| [28] | Liu C H, Gao C, Yan D Y. Macromolecules, 2006, 39: 8102-8111
|
| [29] | Radowski M R, Shukla A, von Berlepsch H, Bottcher C, Pickaert G, Rehage H, Haag R. Angew. Chem. Int. Ed., 2007, 46: 1265-1269
|
| [30] | Tang L M, Fang Y, Tang X L. J. Polym. Sci. Part A: Polym. Chem., 2005, 43: 2921-2930
|
| [31] | Satoh T. Soft Mater, 2009, 5: 1972-1982
|
| [32] | Lou X L, Cheng F, Cao P F, Tang Q, Liu H J, Chen Y. Chem. Eur. J., 2009, 43: 11566-11572
|
| [33] | Tian W, Fan X D, Kong J, Liu Y Y, Liu T, Huang Y. Polymer, 2010, 51: 2556-2564
|
| [34] | Chauhan A S, Sridevi S, Chalasani K B, Jain A K, Jain S K, Jain N K, Diwan P V. J. Controlled Release, 2003, 90: 335-343
|
| [35] | Liu M J, Kono K, Frechent J M J. J. Controlled Release, 2000, 65: 121-131
|
| [36] | Beer P D, Gale P A. Angew. Chem. Int. Ed., 2001, 40: 486-516
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
