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化学进展 2014

几类过渡金属配合物催化的烯烃硅氢化反应机理

DOI: 10.7536/PC130745, PP. 345-357

赵艳,郭彩红,武海顺

Keywords: 过渡金属配合物,催化剂,烯烃,硅氢化,反应机理

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Abstract:

有机硅材料是一种功能独特，性能优异的化工新材料，广泛应用于工业、农业、医药等各大领域。其种类繁多，如硅油、硅橡胶、硅树脂、硅烷等，它们的主要成分均为有机硅化合物，且均非自然界中存在的天然物质，需人工合成。目前，烯烃硅氢化反应是制备有机硅化合物的重要方法之一。该方法简单而直接，且具有原子经济性，备受人们的亲睐。这类反应需要在催化剂的作用下才能发生，因而过渡金属催化剂的设计和机理的研究一直为实验和理论工作者所关注。本文综述了近年来过渡金属配合物催化剂及其催化烯烃硅氢化反应的机理。重点介绍了Pt、Rh、Ru、Zr等过渡金属配合物的不同催化作用机制，希望为以后的研究提供思路和启发。

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