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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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功能性POSS聚合物及其应用
DOI: 10.7536/PC130759, PP. 394-402
Keywords: POSS,超疏水表面,抗结冰,两亲聚合物,形状记忆高分子
Abstract:
多面体低聚倍半硅氧烷（POSS）是一类具有纳米分子尺寸和有机-无机杂化结构的化合物。这种以无机Si—O—Si键组成的框架为核，外围被有机取代基所包围的特殊结构，具有独特的物理性质和化学反应性。采用物理或共聚的方法使其与其他聚合物复合，得到具有特殊功能的有机/无机纳米复合高分子材料，可用于诸多领域，近年来备受关注。本文在介绍POSS分子结构特点的基础上，详细阐述POSS聚合物的合成方法、特点和功能性，着重讨论了POSS在超疏水表面与抗结冰涂层、两亲聚合物、形状记忆材料中的应用及研究现状，并展望了功能性POSS聚合物的发展前景。
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