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化学进展 2014

醇-胺直接脱氢及氧化脱氢偶联酰胺化反应

DOI: 10.7536/PC130740, PP. 334-344

马文婵,周乔,张月成,赵继全

Keywords: 脱氢偶联,醇,胺,酰胺,PNN-Ru配合物,NHC-Ru配合物,负载金

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Abstract:

醇-胺（氨）直接脱氢及氧化脱氢偶联生成酰胺具有原子经济性高和对环境友好等优点，因而受到广泛关注。研究发现，一些过渡金属钌及铑配合物、负载金及银纳米粒子、氧化锰分子筛（OMS-2）以及基于铜、铁化合物的催化体系在醇-胺（氨）直接脱氢或氧化脱氢偶联生成酰胺反应中显示出优良的催化性能。本文首先介绍了PNN-钌、NHC-钌配合物、铑配合物以及负载银原子簇催化的醇-胺（氨）直接脱氢偶联生成酰胺反应的研究进展，然后对负载纳米金粒子、氧化锰分子筛（OMS-2）以及基于铜、铁化合物的催化体系催化的不同氧化剂，包括分子氧、叔丁基过氧化氢以及分子碘氧化的氧化酰胺化反应进行了总结。对各催化剂或催化体系的适用范围和优缺点进行了分析，阐述了主要催化剂或催化体系的催化机理。此外，还对无过渡金属参与的醇-胺氧化酰胺化反应体系进行概述。最后，在总结现有成果的基础上指出了该领域的发展方向。

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