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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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液体有机氢化物储氢研究进展*
, PP. 2760-2770
Keywords: 液体有机氢化物,储氢,脱氢催化剂,催化脱氢反应模式
Abstract:
液体有机氢化物储氢技术利用不饱和液态芳烃和对应环烷烃之间的加\脱氢反应，不仅可用于长周期的季节性储氢，还可用于远距离输氢，以解决地区间能源分布不均的问题。本文分析了该技术的基本原理和特点，并着重就其中的脱氢反应，从催化剂的开发、催化反应机理以及反应模式等层面，进行了分析讨论。关于催化剂，主要从催化剂的活性组分、颗粒分散度、载体种类、孔结构和表面性质与催化活性、结焦失活和耐硫性之间关系的关系进行了分析。关于反应模式，重点讨论了过热液膜态反应、非稳态脉冲喷射进料反应和膜分离反应等几种有利于改善传热传质条件、打破平衡限制的催化脱氢反应模式。并展望了液体有机氢化物储氢的研究和发展方向。
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