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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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双金属氰化络合物及其催化的聚合反应
, PP. 1776-1784
Keywords: 锌-钴双金属氰化络合物,催化,聚合
Abstract:
本文综述了双金属氰化络合物及其催化的环氧化物参与的聚合反应研究。双金属氰化络合物是由其内界金属MⅡ通过氰基与外界金属MⅠ连接形成的含MⅡ—C≡N-MⅠ桥键的三维网络状无机高分子(MⅠ一般为Zn2+、Fe2+、Co2+和Ni2+等二价金属离子,MⅡ一般为Fe2+、Fe3+、Co2+、Co3+和Ni2+等过渡金属离子)。外界金属MⅠ一般被认为是催化反应的活性中心金属。该类催化剂早期被用于催化环氧化物开环聚合,并逐步发展成为合成中高分子量、低不饱和度聚醚多元醇的极高效催化剂。近年来该类催化剂被用来催化环氧化物/环状酸酐共聚、环氧化物/CX2(X≡O,S)共聚和环氧化物/环状酸酐/CO2三元共聚反应合成聚酯、聚碳酸酯、聚(醚-碳酸酯)、聚硫代碳酸酯和聚(碳酸酯-酯)等具有生物降解性的聚合物。尤其对氧化环己烯(CHO)与CO2(或酸酐)共聚,锌-钴双金属氰化络合物表现出了极高的催化活性和选择性。结合本研究组十多年的研究结果,本文讨论了双金属氰化络合物催化活性中心的可能结构和催化机理,提出了双金属氰化络合物催化聚合的共性难题和解决这些问题的方向。
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