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化学进展  2012 

锆酸钙基高温质子导体材料

, PP. 1845-1856

Keywords: 锆酸钙,高温质子导体,材料制备方法,陶瓷烧结工艺,质子传输机理,晶界设计

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Abstract:

锆酸钙基材料具有优良的热、机械、发光、介电性能,是先进的耐火、发光、铁电材料。自1991年Iwahara等发现锆酸钙基材料在高温下具有质子导电性以来,锆酸钙基电解质陶瓷的研究取得重大进展。本文结合本实验室的研究分别从材料制备、陶瓷烧结、质子传输机理及影响质子传输的因素等4个方面就20年来锆酸钙基质子导体材料的研究进展进行了综述,并对其未来发展进行了展望。

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