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化学进展  2011 

富勒烯合成化学研究进展

, PP. 53-64

Keywords: 富勒烯,合成,结构,内嵌富勒烯,笼外化学修饰,IPR规则,氮杂富勒烯

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Abstract:

富勒烯是一类由12个五元环和若干六元环组成的笼状分子,自20世纪80年代中期被发现以来就以其独特的结构和新奇的性质而成为科学界研究的热点,25年来,无论在基础研究还是在实际应用领域都有了长足的进步,人们在发展富勒烯合成新方法和寻找富勒烯新结构方面做了大量的工作。本文对富勒烯的各种宏量合成方法进行了回顾,并概述了迄今已发表的60余种富勒烯新结构,包括各种富勒烯空笼、内嵌富勒烯、富勒烯笼外修饰衍生物及氮杂富勒烯等结构。

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