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OALib Journal期刊
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原子力显微镜法研究方解石(104)面的生长及溶解
, PP. 107-124
Keywords: 生物矿化,方解石,原子力显微镜,有机添加剂
Abstract:
研究生物矿化过程及生物矿物的形成机制具有重要的科学意义,这方面的研究不仅有助于我们认识自然,而且还可以指导体外仿生合成具有分级结构的功能性复合材料。原子力显微镜(atomicforcemicroscope,AFM)是微米、纳米尺度上实时观测矿物成核或生长的强有力工具。本文综述了原子力显微镜法研究方解石(104)面生长及溶解的最新进展,重点论述了有机添加剂对(104)面生长和溶解的影响,讨论了添加剂分子与方解石晶面间的作用方式和机制,为理解生物矿物的形成机理提供了新的启示。已有的研究表明,有机添加剂可通过与方解石(104)面的位点专一性作用改变晶体微粒从溶液相进入晶体相的能垒、台阶边缘自由能及(104)表面活性位的数目,从而改变台阶的生长动力学,以致影响晶体的整体形貌。最后,本文对今后方解石生物矿化的研究重点进行了展望。
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