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氢氧化铝含量对硅橡胶结构及憎水恢复性的影响

DOI: 10.13336/j.1003-6520.hve.2015.02.016, PP. 468-473

Keywords: 憎水恢复,氢氧化铝,硅橡胶,正电子寿命谱,等离子体,自由体积

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Abstract:

氢氧化铝(ATH)作为阻燃剂是复合绝缘子硅橡胶的基本原料。为研究ATH含量对硅橡胶结构和憎水恢复性的影响,炼制ATH质量分数分别为40%、45%、50%和55%的硅橡胶试样,对试样进行正电子寿命谱、邵氏硬度测试,及5minAr等离子体老化实验。结果表明ATH质量分数从40%增加到55%时,次长寿命强度I3从7.8%下降到6.1%,而最长寿命强度I4从24.8%锐减至18.6%。随ATH质量分数增加,硅橡胶中2种自由体积的尺寸基本不变;但ATH颗粒容易发生团聚,这些颗粒占据了分子链运动空间,限制了大分子链的运动,使得大尺寸自由体积数量减少,特别是使大尺寸孔洞的数量锐减。邵氏硬度随ATH质量分数增大而变大,说明样品由弹性体朝无机体转变。经相同等离子体处理时间后,硅橡胶憎水恢复速度随ATH质量分数增加而减慢,结合正电子湮没寿命结果可知,ATH的加入限制了体系内硅橡胶分子链的运动,自由体积数量减少,使得小分子输送通道变少。

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