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土壤pH值对冻融黑土重金属Cd赋存形态的影响

Keywords: 重金属Cd,形态转化,pH值,冻融循环,黑土

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Abstract:

冻融作用对不同土壤pH值的重金属Cd赋存形态的转化产生显著影响,以24h为一个冻融周期,对2.5mgCd·kg-1的黑土冻融8次的实验结果表明,pH值6.0~4.5时,冻融作用促进重金属交换态和有机结合态Cd含量增加,铁锰氧化物结合态和残渣态Cd含量降低;pH值6.0~9.5时,冻融作用促进交换态和有机结合态Cd含量降低,铁锰氧化物结合态和残渣态Cd含量增高。从重金属Cd赋存形态的转化可得,随着土壤pH值的升高,冻融作用促进重金属Cd生物有效态含量降低。

References

[1]  龚家栋,祁旭升,谢忠奎,等.季节性冻融对土壤水分的作用及其在农业生产中的意义[J].冰川冻土,1997,19(4):328-333.
[2]  Shoop S A,Bigl S R.Moisture migration during freeze and thaw of unsat-urated soils:modeling and large scale experiments[J].Cold Regions Sci-ence and Technology,1997,25:33-45.
[3]  赵林,程国栋,丁永建.中国冻土研究进展[J].地理学报(英文版),2004,14(4):411-416
[4]  王铁宇,汪景宽,周敏,等.黑土重金属元素局地分异及环境风险[J].农业环境科学学报,2004,23(2):272-276.
[5]  王新,周启星.土壤重金属污染生态过程、效应及修复[J].生态科学,2004,23(3):278-281.
[6]  Alloway B J.Soil processes and the behavior of heavy metals[M]//Heavy metals in soils,(Seeond Edition)(Alloway B J,ed.) Blackie,New York.1995.11-37.
[7]  Brummer R S,Gerth J,Tiller G.Reaction kinetics of the adsorption of nickel,zine,and cadmium by goethite:Ⅰ.Adsorption and diffusion of metals[J].Journal of Soil Science,1988,23:134-142.
[8]  王洋,刘景双,王国平,等.冻融作用与土壤理化效应的关系研究[J].地理与地理信息科学,2007,23(2):91-96.
[9]  盂献玺,李生智.吉林省土壤元素背景值研究[M].北京:科学出版社,1995.101-102.
[10]  GB15618-1995,土壤环境质量标准[S].
[11]  夏增禄.中国土壤环境容量[M].北京:地震出版社,1992.37-38.
[12]  Tessier A,Campbell P G,Blsson M.Sequential extraction procedure for the speeiation of particulate trace metals[J].Analysis Chemical,1979,51:844-851.
[13]  廖敏,黄昌勇,谢正苗.pH对镉在土水系统中的迁移和形态的影响[J].环境科学学报.1999,19(1):81-86.
[14]  El-Falaky A A,Aboulreos S A,Lindsay W L.Measurement of cadmium activities in slightly acidic to alkaline soil[J].Science Society of America Journal,1991,55:974-979.
[15]  Benjamin M M,Leckie J O.Multiple-site adsorption of Cd,Cu,Zn and Pb on amorphous iron oxyhydroxide[J].Journal of Colloid lnterface Sci-ence,1981,79:209-221.
[16]  Hassink J.Effects of soil texture and structure on carbon and nitrogen mineralization in grassland soils[J].Biology and Fertility of Soils,1992,14:126-134.
[17]  Sehimel J P,Clein J S.Microbial response to freeze-thaw cycles in tundra and taiga soils[J].Soil Biology and Biochemistry,1996,28:1061-1066.
[18]  Wang Z,Delaune R D,Masschelegn P H,et al.Soil redox and pH ef-fects on methane production in a flooded rice soil[J].Soil Science So-ciety of America Journal,1993,57:382-385.
[19]  Groeneweg J,Sellner B,Tappe W.Ammonia oxidation in nitrosomonas at NH3 concentrations near Km:effects of pH and temperature[J].Water Research,1994,28(12):2561-2566.
[20]  贾建业,兰斌明,谢先德,等.硫化物矿物溶解度与溶液pH值的关系[J].长春科技大学学报,2001,31(3):241-246.
[21]  Lehrseh G A.Freeze-thaw cycles increase near-anfface aggregate stability[J].Journal of Soil Science,1998,163:63-70.
[22]  Taskin O,Ferhan F.Effect of freezing and thawing processes on soil ag-gregate stability[J].CA TENA,2003,52:1-8.

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