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EDTA对饱和多孔介质中纳米银迁移机制的影响

DOI: 10.11654/jaes.2015.08.020

Keywords: 纳米银 饱和多孔介质 乙二胺四乙酸(EDTA) 迁移

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Abstract:

通过混合批实验及三脉冲饱和砂柱实验,研究了1 mmol·L-1及300 mmol·L-1离子强度下 EDTA 与聚乙烯吡咯烷酮(PVP)修饰的纳米银颗粒的相互作用机制及其对纳米银颗粒在石英砂柱和铁氧化物涂层石英砂柱中迁移行为的影响。批实验结果表明:高、低离子强度下,EDTA均能置换纳米银颗粒表面的PVP聚合物,使稳定纳米银颗粒的机理由PVP产生的空间位阻作用转变为EDTA产生的双电层稳定效应。柱实验结果表明:高离子强度降低纳米银内核与石英砂之间的双电层排斥作用,进而降低其迁移性能;铁氧化物涂层减少了石英砂面上纳米银的点位从而降低其沉降速率;EDTA对砂柱的淋洗未能明显释放沉积态纳米银,但可通过络合并溶解铁氧化物石英砂表面的铁氧涂层促进纳米银沉降

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