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天津于桥水库沉积物理化特征及磷赋存形态研究

Keywords: 沉积物,磷赋存形态,理化特征,水库调水

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Abstract:

以天津于桥水库作为我国北方湖泊的代表,应用淡水沉积物磷形态的标准测试程序(SMT)对于桥水库6个表层沉积物样品的理化特征及磷赋存形态进行分析,并在此基础上探讨了各形态磷之间及各形态磷与沉积物理化特征,如阳离子交换量、有机质总量、颗粒组成、主要金属含量之间的相关性。结果表明,研究区域内总磷含量为354~581mg·kg-1,其中以无机磷(IP)为主;占总磷含量的57.3%~74.7%;3种主要磷形态含量的大小依次为Ca-P>OP>Al/Fe-P,其中Ca-P是沉积物中磷的主要赋存形态;随着沉积物中有机磷含量的增加,有机质总量与阳离子交换量也逐渐提高,细粉粒(0.01~0.005mm)的含量也有所增加。此外,还对水库调水前后沉积物磷赋存形态的变化进行了研究,发现沉积物在调水期间主要扮演“汇”的角色,其中Fe/Al-P为调水期内变化最为活跃的磷形态。

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