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柠檬酸/柠檬酸钠淋洗铬污染土壤效果及弱酸可提取态铬含量的变化

Keywords: ,柠檬酸,柠檬酸钠,复合淋洗剂,弱酸可提取态

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Abstract:

研究了用0.2mol·L-1柠檬酸/柠檬酸钠(摩尔比为1∶1)复合淋洗剂对污染土壤中铬的淋洗效果,及淋洗过程中Cr(Ⅵ)和Cr(Ⅲ)以及弱酸可提取态的含量随淋洗时间的变化,污染土壤取自于沈阳市沈北新区铬渣堆放场地污染土壤。结果表明,在该复合淋洗剂的解吸附与络合的双重作用下,总铬的短时间去除效率较高,淋洗8h和24h的去除率分别为33.6%和36.0%,其中淋洗24h时Cr(Ⅵ)和Cr(Ⅲ)的去除率分别达到38.5%和30.0%。淋洗过程中土壤中铬的形态发生了重新分配,弱酸可提取态占总铬比例增加,从而有利于铬在土壤中的迁移。

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