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臭氧洗消化学战剂模拟剂DPCP试验研究

Keywords: 臭氧,洗消,化学战剂,模拟剂,DPCP

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Abstract:

用臭氧对神经性化学战剂的模拟剂氯磷酸二苯酯(DPCP)进行洗消,试验考察了初始酸度、O2流量、放电功率、放电室压力、反应温度、初始浓度和O3流量等因素对DPCP降解率的影响。碱性条件下DPCP降解率高于酸性条件下的降解率;反应温度、O3流量、放电功率的增加,DPCP降解率上升;初始浓度增加,DPCP降解率下降;氧气流量和放电室压力增加,DPCP降解率先上升,后下降。在最佳反应条件下,50mg/L的DPCP处理16min降解率达到98%,矿化率40.1%。

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