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酸度对好氧颗粒污泥生物吸附含铅废水影响的研究

Keywords: 好氧颗粒污泥,Pb2+,离子交换,生物吸附,解析

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Abstract:

为了有效地控制铅污染,利用序批式反应器(sequencingbatchreactor,SBR)培养的以醋酸钠为碳源的好氧颗粒污泥作为吸附剂,进行生物吸附含铅废水的效能和机理的研究。通过考察酸度、接触时间和Pb2+初始浓度等因素的影响,验证好氧颗粒污泥吸附模型,并利用不同的脱附剂,进一步解析其生物吸附的Pb2+。实验结果表明,酸度是影响好氧颗粒污泥生物吸附Pb2+的关键因素,当初始pH为5时,好氧颗粒污泥对含铅废水生物吸附效果最好。对低浓度(0~20mg/L)含铅废水,10min后可快速达到吸附平衡。好氧颗粒污泥对Pb2+的实测饱和吸附量为101.97±9.00mg/g,符合朗缪尔(Langmuir)模型。好氧颗粒污泥生物吸附Pb2+的过程,伴随着pH值的升高和K+、Ca2+、Mg2+的释放,此现象揭示离子交换作用是好氧颗粒污泥生物吸附Pb2+的机理之一。此外,脱附剂HNO3、EDTA和CaCl2能实现Pb2+的回收和好氧颗粒污泥的重复利用。

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