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水中安替比林的紫外光降解研究

Keywords: 安替比林,光降解,紫外光

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Abstract:

以波长为254nm的紫外杀菌灯为光源,研究了水溶液中消炎镇痛药物安替比林(PZ)的光降解行为;考察了初始pH值及水中其他物质对PZ光降解的影响,探讨了PZ光解机制,并分析其降解产物及光解途径。结果表明,安替比林的光降解遵循拟一级反应动力学规律,pH值变化对光解速率基本没有影响。安替比林直接光降解占主导作用,活性氧类物种(ROS)对安替比林间接光解基本没有贡献。腐殖酸对安替比林光降解有抑制作用,而NO-3,HCO-3,Cl-对安替比林光降解没有明显作用。GC-MS分析表明安替比林在紫外辐射下生成甲酰胺,乙酰胺,2-羟基吲哚-3-酮,2,4(1氢,3甲基)-喹唑啉二酮,1-甲基-2-羟基苯并咪唑,2-羟基苯并恶唑等一系列具有安替比林母体苯环结构的化合物,表明安替比林侧链上N—N键断裂导致其最终降解。

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