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甲基红在壳聚糖上吸附富集的研究

Keywords: 甲基红,壳聚糖,吸附富集,动力学,热力学

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Abstract:

研究了pH、初始浓度、时间及温度对甲基红在壳聚糖上吸附富集的影响。结果表明,pH是影响甲基红吸附富集的重要因素,最佳pH3.4。其动力学行为更好地符合Lagergren准二级反应动力学模型,随着温度增加,平衡吸附量减少。吸附过程的表观活化能(Ea)为7.518kJ/mol。壳聚糖对甲基红的吸附过程较好地符合Freundlich吸附等温方程。计算得到吸附过程的热力学参数ΔGo、ΔHo和ΔSo分别为-24.88kJ/mol(303K)、-22.15kJ/mol和8.783J/(mol?K),表明壳聚糖对甲基红的吸附是一个自发的放热过程。红外光谱分析得到,壳聚糖吸附甲基红的过程中,壳聚糖分子中存在的大量羟基和氨基发挥了主要作用。

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