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气相介质阻挡放电氧化降解酸性红88的机理

Keywords: 介质阻挡放电,氧化降解,酸性红88,机理分析

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Abstract:

为了有效处理难生物降解的染料废水,采用气相介质阻挡放电产生以羟基自由基为主的氧化性物质,对偶氮染料酸性红88(AR88)进行了氧化降解,并对放电过程中各化学效应对AR88降解的作用机理进行了分析。结果表明,当用相对湿度100%的空气为气源时,放电过程中生成的活性物种如OH?、O3和H2O2是引起放电过程中AR88氧化降解反应的主体,其中OH?在AR88的降解过程中起主要作用,O3参与了对AR88的氧化降解,H2O2对AR88的降解没有明显作用。采用GC/MS分析AR88的主要降解中间产物为萘磺酸、1,2-萘醌、1,2-苯并吡喃酮、萘酚和邻苯二甲酸。通过产物测定和前线电子密度理论,推测了降解途径。

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