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热处理和pH调节协同作用下污泥调质过程研究

Keywords: 污泥,热碱处理,溶解性化学需氧量,分子量分布

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Abstract:

采用单因素实验和正交实验相结合的方式,考察了不同实验条件参数(温度、pH和反应时间)下,热处理和pH调节对污泥细胞溶出过程的影响。结果表明,污泥溶解性化学需氧量(SCOD)与反应温度、溶液pH、反应时间成正相关,其中pH对SCOD的影响最为显著,反应时间对其影响最小。污泥溶胞的最优条件:反应温度120℃,pH=11,反应时间为15min,经过处理,SCOD可达14810mg/L,与总化学需氧量(TCOD)之比为49.29%,总有机碳(TOC)达4560mg/L,总氮(TN)则增加27%,总悬浮固体(TSS)和挥发性悬浮固体(VSS)去除率分别达22.85%和40.93%。热碱处理后污泥上清液分子量分布(MWD)状况结果显示:>1000KDaMW物质含量随pH和温度的增加而增加,当pH=11时,该部分物质可从原污泥的20.94%增加到31.70%;当温度为120℃时,该部分物质可达49.83%。

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