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粉煤灰基沸石对亚甲基蓝和Cr(Ⅲ)的共吸附行为——Ⅰ. 吸附动力学和吸附热力学

Keywords: 共吸附,合成沸石,亚甲基蓝,Cr(Ⅲ)

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Abstract:

以粉煤灰为原料,采用优化改进的水热晶化一步法合成沸石。借助FTIR、XRD和SEM对沸石理化特性进行表征,分析水中双组分污染物亚甲基蓝(MB)和Cr(Ⅲ)的共吸附去除特性。结果表明,合成沸石产物呈菱形或多面体形,在XRD图谱中可见NaP1型沸石特征峰。共吸附过程为准二级反应,以化学吸附为速率控制步骤。Langmuir和Freundlich等温线方程都能有效地描述反应过程,298K条件下,沸石对MB和Cr(Ⅲ)的理论最大吸附量分别为7.8186mg/g和8.8889mg/g。吸附过程自发、吸热,反应后体系自由度降低,推测吸附位点的直接竞争为MB和Cr(Ⅲ)去除的主导机制之一。

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