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乌梁素海沉积物孔隙水中溶解有机质的荧光及紫外光谱研究

Keywords: 水溶性有机质,腐殖化程度,芳香构化程度,荧光指数

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Abstract:

运用紫外可见光吸收光谱与荧光光谱研究乌梁素海沉积物孔隙水中溶解有机质的来源、结构及腐殖化程度。r(A,C)、HIX、SUVA280和SUVA254等被用于表征DOM的腐殖化程度和芳香构化程度及结构,f450/500用于指示DOM的来源。研究结果表明:腐殖化程度最高的点为湖泊东部的W4样点,腐殖化程度最低的为总排干影响区域的W1样点。E253/203表明湖泊入口处沉积物孔隙水中有机质主要为不可取代的芳香环结构。荧光指数f450/500为1.57~1.82之间。总体而言,f450/500的值更接近于1.6,处于2个端源中间,说明乌梁素海DOM中的腐殖质主要来源于陆源输入。相关分析的结果表明,DOM的不同来源对其腐殖化程度产生影响。随着腐殖化值的增大,DOM的来源由生物源向陆源过渡。

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