丙酸预处理小麦秸秆的纤维素水解动力学
DOI: 10.6041/j.issn.1000-1298.2012.09.021, PP. 111-115
Keywords: 小麦秸秆,纤维素,丙酸,水解动力学
Abstract:
利用丙酸法预处理小麦秸秆,测定了不同温度下反应产物中葡萄糖质量浓度,并根据Saeman模型,计算得到了纤维素水解和葡萄糖降解的动力学数据,其活化能分别为6.5086×104J/mol和5.6223×104J/mol。动力学分析表明:纤维素水解反应速度快,但是生成的葡萄糖容易发生降解;该模型的最优化反应条件为80℃和176min,实验得到的葡萄糖质量浓度为8.89g/L,与模型预测结果偏差很小。
References
[1] | Zhang Y;Himmel E M;Mielenz J R Outlook for cellulose improvement screening and selection strategies 2006(5)
|
[2] | Silverstein R A;Chen Y;Sharma R Acomparison of chemical pretreatment methods for improving saccharification of cotton stalks 2007(16)
|
[3] | Maloney M T;Chapman T W;Baker A J Dilute acid hydrolysis of paper birch:kinetic study of xylan and acetyl-group hydrolysis 1985(3)
|
[4] | 胡湛波;王景全;柴欣生 一种用紫外光谱测定混合糖含量的新方法 2008(5)
|
[5] | 金强;张红漫;徐锐 半纤维素稀酸循环喷淋冲滤水解动力学 2011(1)
|
[6] | 白从广;刘学军;王燕 微波辐照木糖降解制备糠醛反应动力学 2010(3)
|
[7] | 李琰;任秀珍;亓伟 生物质稀酸水解技术研究进展 2009(4)
|
[8] | Saeman J F Kinetics of wood hydrolysis-decomposition of sugars in dilute acid at high temperature 1945(1)
|
[9] | Bustos G;Ramírez J A;Garrote G Modeling of the hydrolysis of sugarcane bagasse with hydrochloric acid 2003(1)
|
[10] | Liao W;Liu Y;Liu C Acid hydrolysis of fibers from dairy manure 2006(14)
|
[11] | Aguilar R;Ramírez J A;Garrote G Kinetic study of the acid hydrolysis of sugarcane bagasse 2002(4)
|
[12] | Gámez S;González C J;Ramírez J A Study of the hydrolysis of sugarcane bagasse using phosphoric acid 2006(1)
|
[13] | Eken S N;Mutlu S F;Dilma(c) (C) Acomparative kinetic study of acidic hemicellulose hydrolysis in corn cob and sunflower seed hull 1998(2)
|
Full-Text