Mar and abrasion resistance were investigated by a progressive load scratch test and steel wool abrasion test, respectively. Two acrylic coating systems including trimethylolpropane triacrylate (TMPTA) and pentaerythritol triacrylate (PETA) were prepared. A soft base layer was introduced as an intermediate layer between two different types of top layer and poly (methyl methacrylate) (PMMA) substrate to demonstrate the effect of soft base layer on mar and abrasion resistance. Abrasion damage on the coating surface was found to be less severe, when the soft base layer was incorporated into the coating systems. The reduction in scratch coefficient of friction (SCOF) and surface roughness was also observed. The results suggested that mar and abrasion resistance was greatly influenced by the presence of soft base layer, although different top layers were used. Moreover, it was found that abrasion resistance was further improved as the thicker soft base layer was applied.
References
[1]
Schottner, G., Rose, K. and Posset, U. (2003) Scratch and Abrasion Resistant Coatings on Plastic Lenses—State of the Art, Current Developments and Perspectives. Journal of Sol-Gel Science and Technology, 27, 71-79. http://dx.doi.org/10.1023/A:1022684011222
[2]
Schulz, U., Volker, W., Thomas, K. and Paul, A. (2001) The Influence of Weathering on Scratches and on Scratch and Mar Resistance of Automotive Coatings. Progress in Organic Coatings, 42, 38-48. http://dx.doi.org/10.1016/S0300-9440(01)00148-5
[3]
Hozumi, A., Kato, Y. and Takai, O. (1996) Two-Layer Hard Coatings on Transparent Resin Substrates for Improvement of Abrasion Resistance. Surface and Coatings Technology, 82, 16-22. http://dx.doi.org/10.1016/0257-8972(95)02643-6
[4]
Mackenzie, J.D. and Bescher, E. (2003) Some Factors Governing the Coating of Organic Polymers by Sol-Gel Derived Hybrid Materials. Journal of Sol-Gel Science and Technology, 27, 7-14. http://dx.doi.org/10.1023/A:1022659323517
[5]
Rao, K.N. (2003) Studies on Thin Film Materials on Acrylics for Optical Applications. Bulletin of Materials Science, 26, 239-245. http://dx.doi.org/10.1007/BF02707798
[6]
Wouters, M.E.L., Wolfs, D.P., van der Linde, M.C., Hovens, J.H.P. and Tinnemans, A.H.A. (2004) Transparent UV Curable Antistatic Hybrid Coatings on Polycarbonate Prepared by the Sol-Gel Method. Progress in Organic Coatings, 51, 312-319. http://dx.doi.org/10.1016/j.porgcoat.2004.07.020
[7]
Kim, S.W. (2010) Characterization of UV Curable Hybrid Hard Coating Materials Prepared by Sol-Gel Method. Korean Journal of Chemical Engineering, 28, 298-303. http://dx.doi.org/10.1007/s11814-010-0338-9
[8]
Gilberts, J., Tinnemans, A.H.A., Hogerheide, M.P. and Koster, T.P.M. (1998) UV Curable Hard Transparent Hybrid Coating Materials on Polycarbonate Prepared by the Sol-Gel Method. Journal of Sol-Gel Science and Technology, 11, 153-159. http://dx.doi.org/10.1023/A:1008693413965
[9]
Schroeter, S.H. and Daniel, R.O. (1980) Abrasion Resistant Silicone Coated Polycarbonate Article. US Patent No. 4210699.
[10]
Ogawa, M. and Hara, Y. (1988) Silicone-Based Coating Composition for Surface-Releasing Film. US Patent No. 4764576.
[11]
Azuma, I., Kosaka, N., Iwamura, G., Marutani, Y. and Uemura, H. (1997) Acrylic Oligomer for High Solid Automotive Top Coating System Having Excellent Acid Resistance. Progress in Organic Coatings, 32, 1-7. http://dx.doi.org/10.1016/S0300-9440(97)00073-8
[12]
Wu, L., Guo, X. and Zhang, J. (2014) Abrasive Resistant Coatings—A Review. Lubricants, 2, 66-89. http://dx.doi.org/10.3390/lubricants2020066
[13]
Friedrich, K. and Schlarb, A.K. (2013) Tribology of Polymeric Nanocomposites: Friction and Wear of Bulk Materials and Coatings. Butterworth-Heinemann, Oxford.
[14]
Holmberg, K., Matthews, A. and Ronkainen, H. (1998) Coatings Tribology—Contact Mechanisms and Surface Design. Tribology International, 31, 107-120. http://dx.doi.org/10.1016/S0301-679X(98)00013-9
[15]
Sidorenko, A., Ahn, H.-S., Kim, D.-I., Yang, H. and Tsukruk, V.V. (2002) Wear Stability of Polymer Nanocomposite Coatings with Trilayer Architecture. Wear, 252, 946-955. http://dx.doi.org/10.1016/S0043-1648(02)00048-0
[16]
Gotlib-Vainshtein, K., Girshevitz, O., Sukenik, C.N., Barlam, D. and Cohen, S.R. (2014) A Nanometric Cushion for Enhancing Scratch and Wear Resistance of Hard Films. Beilstein Journal of Nanotechnology, 5, 1005-1015. http://dx.doi.org/10.3762/bjnano.5.114
[17]
Browning, R., Lim, G.T., Moyse, A., Sun, L. and Sue, H.-J. (2006) Effects of Slip Agent and Talc Surface-Treatment on the Scratch Behavior of Thermoplastic Olefins. Polymer Engineering & Science, 46, 601-608. http://dx.doi.org/10.1002/pen.20507
[18]
Lörinczová, I. and Decker, C. (2014) Scratch Resistance of UV-Cured Acrylic Clearcoats. Surface Coatings International Part B: Coatings Transactions, 89, 133-143. http://dx.doi.org/10.1007/BF02699643
[19]
Jiang, H., Browning, R.L., Hossain, M.M., Sue, H.-J. and Fujiwara, M. (2010) Quantitative Evaluation of Scratch Visibility Resistance of Polymers. Applied Surface Science, 256, 6324-6329. http://dx.doi.org/10.1016/j.apsusc.2010.04.011
[20]
Hossain, M., Browning, M., Minkwitz, R. and Sue, H.-J. (2012) Effect of Asymmetric Constitutive Behavior on Scratch-Induced Deformation of Polymers. Tribology Letters, 47, 113-122. http://dx.doi.org/10.1007/s11249-012-9967-y