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科技导报  2014 

废报纸基纤维素气凝胶的绿色制备及其清理泄漏油污性能

DOI: 10.3981/j.issn.1000-7857.2014.h1.005, PP. 40-44

Keywords: 气凝胶,废报纸,离子液体,吸油

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Abstract:

为制备廉价清洁的吸水吸油性废报纸基纤维素气凝胶(WNCA),使用1-烯丙基-3-甲基咪唑氯盐离子液体(AmImCl)溶解无任何前处理的废报纸,经去离子水、无水乙醇和叔丁醇依次置换即可得纯净的纤维素水凝胶,将其冷冻干燥即可制备柔性的WNCA。采用扫描电子显微镜(SEM)、透射电镜(TEM)和X射线衍射仪(XRD)对制备的WNCA的形态特征、结晶特性及结晶度进行表征分析。结果表明,WNCA具有良好的多孔三维网络交联结构;其晶型结构为纤维素Ⅰ型,结晶度为62.6%,较之所用原料提高了12.8%;该气凝胶能够吸收其自身质量18~20倍的水和废弃污油,通过简单挤压即可把99.8%的液体除去,具备循环利用性能,同时该气凝胶显示了良好的机械性能且可反弹。该研究所用试剂均绿色环保,为绿色气凝胶的制备提供了科学思路。

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