OALib Journal期刊
甲醇溶液直接吸收-离子液体富集-气相色谱-质谱法测定卷烟主流烟气中吡啶、喹啉和苯乙烯
DOI: 10.3724/SP.J.1096.2012.11299
Keywords: 直接吸收 ,离子液体 ,气相色谱-质谱法 ,主流烟气 ,吡啶 ,喹啉 ,苯乙烯
Abstract:
建立了一种收集检测卷烟主流烟气中吡啶、喹啉和苯乙烯的方法,以甲醇(CH3OH)溶液为吸收液,直接收集吸烟机抽吸的卷烟主流烟气,采用PF6离子液体萃取富集,气相色谱-质谱联用(GC/MS)技术定量分析卷烟主流烟气中的吡啶、喹啉和苯乙烯3种半挥发性物质,测定过程简便快速,结果准确可靠。本方法的线性关系良好,相关系数(r2)大于0.9995,吡啶、苯乙烯和喹啉的检出限分别为24.9,9.34和4.05ng/cig(每支烟),相对标准偏差(RSD)小于6.0%,加标回收率在90.6%~107.4%之间。
References
[1] 1 Hoffmann D, Hoffmann I, El-Bayoumy K. Chemistry Research in Toxicology., 2001, 14(7): 767~790 [2] 2 XIE Jian-Ping. Tobacco Perfume,. Beijing: Chemistry Industral Press,2009: 77, 423, 440 [3] 7 LI Rong, CHEN Jing, TANG Gang-Ling, WANG Lei, LI Qun, TONG Xiao-Dong. Chinese Journal of Analysis Laboratory, 2002, 21(5): 31~35 [4] 李 荣, 陈 静, 唐纲岭, 王 蕾, 黎 群, 童晓东. 分析试验室, 2002, 21(5): 31~35 [5] 8 Michael B, Hubert K. Experimental and Toxicologic Pathology, 2005, 57(Suppl. 1): 43~73 [6] 9 CAI Jun-Lan, ZHAO Ming-Yue, CHEN Yong, FENG Li-Ting. Acta Tobacaria Sinca, 2003, 9(4): 1~11 [7] 蔡君兰, 赵明月, 陈 勇, 冯丽婷. 中国烟草学报. 2003, 9(4): 1~11 [8] 10 T-112. Determination of Pyridine, Quinoline and Styrene in Mainstream Tobacco Smoke, Health Canada Test Method, 1999-12-31 [9] 11 Part 7: Validation data Determination of SVC Yields in Mainstream Cigarette Smoke. UK Smoke Constituents Study, 2003 [10] 12 HAN Bing, WANG Hai-Yan. Guangdong Chemical Industry, 2011, 38(7): 148~150 [11] 韩 冰, 王海艳. 广东化工, 2011, 38(7): 148~150 [12] 13 PENG Hui-Min, WU Ming-Jian, REN Feng-Lian, HE Zhi-Hui, LIAN Wen-Liu. Chinese J. Anal. Chem., 2007, 35(2): 289~292 [13] 彭惠敏, 吴名剑, 任凤莲, 何智慧, 练文柳. 分析化学, 2007, 35(2): 289~292 [14] 14 CUI Yang, LI Xue-Mei, YANG Ye-Kun, ZENG Xiao-Ying, ZHE Wei, DUAN Yan-Qing, LI Gan-Peng. Chinese J. Anal. Chem., 2010, 38(2): 275~279 [15] 崔 杨, 李雪梅, 杨叶昆, 曾晓鹰, 者 为, 段焰青, 李干鹏. 分析化学, 2010, 38(2): 275~279 [16] 15 Kulshreshtha N P, Moldoveanu S C. J. Chromatogr. A, 2003, 985(1-2): 303~312 [17] 16 XIAO Xiao-Hua, LIU Shu-Juan, LIU Xia, JIANG Sheng-Xiang. Chinese J. Anal. Chem., 2005, 33(4): 569~574 [18] 谢剑平. 烟草香原料. 北京:化学工业出版社, 2009:77, 423, 440 [19] 3 Christensen A, stman C, Westerholm R. Anal. Bioanal. Chem., 2005, 381(6): 1206~1216 [20] 4 BAI Jun-Chao; LIU Shao-Feng; XIE Fu-Wei; LIU Hui-Min; XIA Qiao-Ling. Chinese Journal of Chromatography, 2010, 28(6): 608~614 [21] 白军超, 刘绍锋, 谢复炜, 刘惠民, 夏巧玲. 色谱, 2010, 28(6): 608~614 [22] 5 PANG Yong-Qiang, WANG Fei, CHEN Zai-Gen, HOU Hong-Wei, HU Qing-Yuan, TANG Gang-Ling. Journal of Chinese Mass Spectrometry Society, 2009, 30(2): 124~128 [23] 庞永强, 王 菲, 陈再根, 侯宏卫, 胡清源, 唐纲岭. 质谱学报. 2009, 30(2): 124~128 [24] 6 Lars-Owe K. Fresenius'' J. Anal. Chem., 1998, 361(8): 791~796 [25] 肖小华, 刘淑娟, 刘 霞, 蒋生祥. 分析化学, 2005, 33(4): 569~574 [26] 17 Eric N, Hoang A H, Stéphane B, Livain B, Daniel B. The Journal of Physical Chem. B, 2002, 106(41): 10585~10593 [27] 18 Intorp M, Purkis S, Whittaker M, Wright W. Beitrge zur Tabakforschung International/Contributions to Tobacco Research, 2009, 23(4): 161~202
Full-Text
Contact Us
service@oalib.com
QQ:3279437679
WhatsApp +8615387084133
