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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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氟代苯硼酸与单糖间结合规律探究
DOI: 10.11895/j.issn.0253-3820.150441, PP. 1459-1464
Keywords: 氟代苯硼酸,单糖,相互作用,亲和毛细管电泳
Abstract:
取代硼酸与顺式二羟基化合物间的相互作用是设计亲和配基、功能材料和传感元件以分离、富集和识别顺式二羟基化合物的重要基础。氟代苯硼酸在较低pH条件下具有较高的硼亲和力,但其与单糖间的相互作用规律目前尚未得到阐明。本研究以亲和毛细管电泳为相互作用表征手段,研究了9种不同结构的氟代苯硼酸与3种典型单糖(甘露糖、果糖和葡萄糖)在不同pH条件下的结合常数。同时,利用紫外分光光度法测量了这9种氟代苯硼酸的酸度系数。经过结构-性能关联,对氟代苯硼酸与甘露糖、果糖和葡萄糖的结合规律以及对葡萄糖的选择性进行了探讨。
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