可溶性聚酰亚胺电化学反应机理的研究
, PP. 147-151
Keywords: 聚酰亚胺,电化学反应,红外光谱,半经验分子轨道计算方法
Abstract:
本文研究了三种可溶性聚酰亚胺(PI)在有机溶剂和水溶液中的电化学行为,发现PI在有机溶剂中的电化学行为明显不同于水溶液.利用红外光谱技术和半经验分子轨道计算方法,结合电化学测试的结果,确证了PI的电化学反应的机理.
References
[1] | 1B ogertTM,RenshawRR.4aminooacidandsomeofitsderivatives.J.Am.chem.Soc.,1908,30:11352HaushalterRC,KrauseLJ.Electrolesmetalizationoforganicpolymersusingthepolymerasaredoxreagent:reactionofpolyimidewithZintlanions.ThinSolidFilms,1983,102,1613MazurS,LuggPS,YanitxkyC,Electrochemistryofaromaticpolyimides.J.Electrochem.Soc.,1987,134,14604ViehbeckA,GoldbergMJ,KovacCA,Electrochemicalpropertiesofpolyimidesandrelatedimidecompounds.J.Electrochem.Soc.,1990,137:14605KrauseLJ,BalesmJL,Electrochemistryofthermalycyclizedpolyimidefilms.J.Electrochem.Soc.,1988,135:11376LiY,DingM,XuJ,Structure,permeabilityandpermselectivityrelationshipofpolyetherimidesfrom1,4bis(3,4dicarboxyphenoxy)benzenedianhydrideⅢ.J.Macro.Sci.PureChem.,1997,A34:461
|
Full-Text