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电化学  1999 

苯酚在热氧化法制备的SnO_2/Ti电极上的电氧化研究

, PP. 401-405

Keywords: 苯酚,电化学氧化,SnO_2/Ti电极,废水处理

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Abstract:

以热氧化法制备的SnO2/Ti电极作为阳极用于含苯酚酸性溶液的恒电流电解,测定了苯酚浓度、溶液中化学需氧量(COD)以及瞬时电流效率等随电解时间的变化.结果表明,用SnO2/Ti电极代替铂作为阳极可使相同氧化电量下的COD明显下降,而平均电流效率提高了3倍.讨论了两种电极上苯酚氧化的反应机理

References

[1]  1  Rajeshwar K,IbanezJG,Swain G M.Electrochemistry and environment,J.Appl.Electrochem .,1994 ,24:1 077~1 091
[2]  2  Simonsson D.Electrochemistryfora cleanerenvironment,Chem .Soc.Rev.,1997 ,26 :181 ~189
[3]  3  Murphy OJ,Hitchens GD,Kaba L.Verostko CE,Direct electrochemical oxidation of organicsfor wastewatertreatment.Wat.Res.,1992 ,26 :443 ~451
[4]  4  Cominellis Ch ,Pulgarin C.Anodic oxidation of phenolfor waste water treatment.J.Appl.Electrochem .,1991 ,21:703~708
[5]  5  Sharifian H,Kirk D W.Electrochemicaloxidation ofphenol.J.Electrochem .Soc.,1986,133:921~924
[6]  6  StuckiS,Kotz R,Carcer B,Suter W.Electrochemical,waste water treatment using high overvoltage anode.J.Appl.Electrochem .,1991 ,21 :99 ~104
[7]  7  Cominellis Ch,Pulgarin C.Electrochemicaloxidation of phenolfor waste watertreatment using SnO2 anodes.J.Appl.Electrochem .,1993 ,23 :108 ~112
[8]  8  Correa_Lozano BCominellis Ch,Battisti ADe.Electrochemical properties of Ti/SnO2_Sb2O5 electrodes preparedbythespray pyrolysistechnique.J.Appl.Electrochem .,1996 ,26 :683 ~688
[9]  9  Houk LL,Johnson SK,Feng J,Houk RS,Johnson DC.Electrochemicalincineration of benzoquinonein aqueous media using a quaternany metal oxide electrodein the absence of a soluble supporting electrolyte.J.Appl.Electrochem .,1998 ,28 :1 167 ~1 177
[10]  10  中国标准出版社总编室,中国国家标准汇编.北京:中国标准出版社,1985
[11]  11  卢里耶.工业污水的化学分析.北京:化学工业出版社,1989 :71
[12]  12  Gattrell M,Kirk D W.Astudy of oxidation of phenolat platinum and preoxidized platinum surfaces.J.Electrochem .Soc.,1993,140:1 534 ~1 541
[13]  13  Rudd EJ,Conway BE.Organic electrode processes.in Comprehensive Treatise of Electrochemistry vol.7(edsConway BEet al.)New York :Plenum ,1983 :641 ~771

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