|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
有机物的阴极间接电氧化(Ⅱ)——烯酸的阴极间接环氧化
, PP. 324-328
Keywords: 阴极间接环氧化,烯酸
Abstract:
建立一种新的阴极间接电氧化体系,以VO(acac)2OOH/VO(acac)2为氧化还原媒质,通过催化阴极由O2电还原产生的H2O2对某些烯酸如顺丁烯二酸、反丁烯二酸和丁烯酸等进行间接环氧化.研究了pH值、温度、电流密度等因素对反应的影响.本文是继前文[1]之后所建立的又一新的氧化还原媒质.此研究对有机电合成的发展具有重要的理论意义和实际意义.
| [1] | [1 ] GuDeng ping ,WangRui zhi,ZhangXue ying .Cathodicindirectoxidationoforganiccompounds(Ⅰ )———electrosynthesisofDMSO2 [J].Electrochemistry (inChinese) ,inpress .
|
| [2] | [6 ] KitamuraM ,YamashitaK ,ImaiH .Studiesonelectrodeprocessesofoxovanadium (Ⅳ ) .Ⅲ .solventeffectonreductionpotetialofvanadylacetylacetonate[J].Chem .Lett .,1 975 ,1 0 71～ 1 0 74.
|
| [3] | Kamaluddin ,SinghHV .Resin supportedvanadium (Ⅳ ) catalysedepoxidationofmaleic ,fumaricandcro tonicacidswithhydrogenperoxide[J].J .Catal.,1 992 ,1 37:5 1 0～ 5 1 2 .
|
| [4] | FuriaFD ,ModenaRecl.G .Metalcatalysisinoxidationbyperoxidespart .5 .onthemechanismofvanadium(Ⅴ )catalysedoxidationbyhydrogenperoxide[J].Trav .Chim .Paysbas ,1 979,98:1 81～ 1 87.
|
| [5] | [2 ] ZhangHong kun ,GuDeng ping .Thetechniquesofthepairedelectrosynthesis[J].Electrochemistry (inChi nese) ,1 999,5 (3) :30 4～ 390 .
|
| [6] | TalsiEP ,ChinakovVD ,BabenkeVP ,etal.Roleofvanadiumalkylperoxocomplexesinepoxidationofcy clohexeneandoxidationofcyclohexanebyorganichydroperoxidesinthepresenceofbis(acetylacetonato)vanadyl[J].J .Mol.Catal.,1 993,81 :2 35～ 2 5 4.
|
| [7] | [4 ] MihelichED .Vanadium Catatyzedepoxidations .Ⅰ .anewselectivitypatternforacyclicalcohols[J].Tera hedronLett.,1 979,49:472 9～ 4732 .
|
| [8] | [5 ] ShengMN ,ZajacekJG .Hydroperoxideoxidationscatalyzedbymetals .Ⅲ .epoxidationofdienesandolefinswithfunctionalgroups[J].J .Org .Chem .,1 970 ,35 (6 ) :1 839～ 1 843.
|
| [9] | LiWei,TsutomaNonaka .Developmentofcathodicoxiditionsystemanditsapplicationtopairedelectrosyn thesisofsulfonesandnitrones[J].J .Electrochem .Soc .,1 999,1 46 (2 ) ,5 92～ 5 97.
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
