OALib Journal期刊
ISSN: 2333-9721
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甲基绿的电化学行为及其与环糊精形成超分子体系研究
, PP. 363-367
Keywords: 甲基绿,环糊精,电流法,超分子
Abstract:
应用“电流法”研究了甲基绿—环糊精超分子体系,测定了甲基绿和4种环糊精的包结常数.其包结能力为HP_β_CD>β_CD>SBE_β_CD>CM_β_CD,包结比为1:2(甲基绿:环糊精)但甲基绿与α_CD和γ_CD不能形成超分子体系.此外,本文还探讨了甲基绿的电极反应机理,初步表明,甲基绿在电极上还原的电子转移数为4,有2个质子参与反应
References
[1] | NakamuraNobuyuki.Productionandapplicationofcyclodextrins[J].Kagakukoygo.1984,35(7):627~634.
|
[2] | LiuShu_qin(刘淑琴),FanHui_zhi(樊惠芝),PanJing_hao(潘景浩).ElectrochemicalofCyclodextrinsandItsInclusionComplexes[M ].Taiyuan:ShamxiScienceandTechnologyPress(inChinese),1997.
|
[3] | YaoXiu_ren(姚修仁),ZhangLi_qun(张立群).SpectraofPolarographicCatalyticCurrent(极谱催化波图谱)[M].Beijing:GeologyPress(inChinese),1988.
|
[4] | GaoXiao_xia(高小霞).PolarographicCatalyticCurrent(极谱催化波)[M ].Beijing:SciencePress(inChi nese),1991.
|
[5] | DongShao_jun(董绍俊),ZhangDong_hai(张东海).StudyoftheInclusionComplexesofCyclodextrinbyCyclicVoltammetry[J].ActaChimicaSinica(inChinese),1988,46:335~339.
|
[6] | WangXP ,PanJH ,LiWH .StudyofTAPPwithcyclodextrinsbypolarography[J].Talanta,2001,54:805.
|
[7] | LavironE .Adsorptionautoinhibitionandautocatalysisinpolarographyandinlinerpotentialsweepvoltammetry[J].J .ElectronalChem,1974,52:370.
|
[8] | BardAJ,FaouknerLR .ElectrochemicalMethods(FundamentalsandApplication)[M ].Newyork:1980,525:96
|
[9] | DingShijia(丁世家),ZhangZuxun(张祖训).Investigationsonpolarographywithlinearlychangingpotential(XV)———TheAdsorptiveComplexwaveofCu(Ⅱ)_L_Adrenaline[J].J .Chem.ChineseUniversity(inChi nese),1991,12(5):598.
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