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电化学  2003 

甲基绿的电化学行为及其与环糊精形成超分子体系研究

, PP. 363-367

Keywords: 甲基绿,环糊精,电流法,超分子

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Abstract:

应用“电流法”研究了甲基绿—环糊精超分子体系,测定了甲基绿和4种环糊精的包结常数.其包结能力为HP_β_CD>β_CD>SBE_β_CD>CM_β_CD,包结比为1:2(甲基绿:环糊精)但甲基绿与α_CD和γ_CD不能形成超分子体系.此外,本文还探讨了甲基绿的电极反应机理,初步表明,甲基绿在电极上还原的电子转移数为4,有2个质子参与反应

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