OALib Journal期刊
ISSN: 2333-9721
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聚间甲氧基苯胺的结构及其氧化还原活性研究
, PP. 205-209
Keywords: 聚间甲氧基苯胺,氧化还原活性
Abstract:
应用循环伏安法研究经HCl、TSA和HClO4等不同酸掺杂的聚间甲氧基苯胺(PmMAn)的电化学活性.结果表明,HClO4是合成PmMAn的最佳酸介质,在此介质中得到的聚合产物具有良好的氧化还原活性.FTIR,SEM和XRD测试分别说明,酸根离子作为抗衡阴离子嵌入PmMAn分子链,并对聚合物的氧化还原活性有较大影响;PmMAn表现出典型的高分子晶体性质,符合单斜晶系的特征.
References
[1] | GazottiJrWA,FaezR,DePaoliMA.Highyieldpreparationofasolublepolyanilinederivative[J].SyntheticMetals,1996,80:263~269.
|
[2] | CattarinS,DoubovaL,MengoliG,etal.Electrosynthesisandpropertiesofring-substitutedpolyaniline[J].ElecrtochimicaActa,1988,33(8):1077~1084.
|
[3] | GazottiJrWA,FaezR,DePaoliMA.Electrochemical,electrochromicandphotoelectrochemicalbehaviorofahighlysolublepolyanilinederivative:poly(o methoxyaniline)dopedwithfunctionalizedorganicacids[J].JournalofElectroanalyticalChemistry,1996,415:107~113.
|
[4] | GazottiJrWA,JanniniMJD,CordobadeTorresiSI,etal.Influenceofdopant,pHandpotentialonthespectralchangesofpoly(o methoxyaniline):relationshipwiththeredoxprocesses[J].JournalofElectroanalyticalChemistry,1997,440:193~199.
|
[5] | LaridjaniM,PougetJP,ScherrEM,etal.Amorphograph-therelationshipbetweenAmorphousandcrystallineorder:1.Thestructuraloriginofmemoryeffectsinpolyaniline[J].Macromolecules,1992,25:4106~4113.
|
[6] | DuicL,MandicZ.Counter-ionandpHeffectontheelectrochemicalsynthesisofpolyaniline[J].JournalofElectroanalysticChemistry,1992,335:207~221.
|
[7] | DuicL,MandicZ,KovacicekF.Theeffectofsupportingelectolyteontheelectochemicalsynthesis,morphology,andconductivityofpolyaniline[J].JournalofPolymerScience,PartA,1994,32:105~111.
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