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电化学  2009 

以Pb-(BrO_3~-/Br~-)为媒介间接电氧化合成双醛淀粉

, PP. 458-461

Keywords: BrO3-/Br-

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Abstract:

应用间接氧化法,以Pb为阳极,BrO3-/Br-为氧化媒介,电氧化淀粉制备双醛淀粉.研究了温度、硫酸与淀粉浓度对电合成过程的影响.在35℃,阳极液WNaBr=2%,CH2SO4=0.05mol/L,W淀粉=10%,电流密度15mA/cm2的实验条件下,电流效率为50%.

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