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电化学  2010 

锂离子电池正极材料Li_3V_2(PO_4)_3的制备及性能研究

, PP. 25-29

Keywords: 锂离子电池,正极材料,Li3V2(PO4)3,电化学性质

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Abstract:

应用碳热还原法制备了表面碳包覆的Li3V2(PO4)3材料.X射线衍射、红外光谱和透射电镜表征样品的结构及形貌.结果表明,该合成样品为纯相的Li3V2(PO4)3晶体,颗粒尺寸100nm左右.电化学阻抗谱测试表明,该材料在3.0~4.3V电位区间的锂离子扩散系数比它在3.0~4.8V区间的高约3个数量级.另外,前者的电荷转移电阻也明显低于后者.因而,其循环性能也明显优于后者的循环性能.

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