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电化学  2012 

LiNi0.49Mn1.49Y0.02O4的合成及其电化学性能研究

, PP. 140-145

Keywords: 锂离子电池,LiNi0.5Mn1.5O4,Y掺杂

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Abstract:

应用柠檬酸辅助溶胶凝胶方法,合成了Y3+取代的尖晶石LiNi0.49Mn1.49Y0.02O4材料.XRD、循环伏安法、恒流充放电和交流阻抗测试结果表明,Y3+的掺杂能提高LiNi0.5Mn1.5O4的倍率和循环性能,在电压区间3.5~4.9V,1C倍率下,其初始容量为114.9mAh?g-1,100次循环后放电比容量仍可达到113mAh?g-1,容量保持率98.3%,掺杂Y3+能减小材料界面阻抗.

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