全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
-  2015 

Pt/C改性的质子交换膜在燃料电池中的应用
Pt/C Modified Proton Exchange Membrane for Improved Fuel Cell Performance

DOI: 10.13208/j.electrochem.141055

Keywords: 质子交换膜,燃料电池性能,相对湿度,高频阻抗,
proton exchange membrane
,PEMFC performance,relative humidity,high frequency resistance

Full-Text   Cite this paper   Add to My Lib

Abstract:

摘要 氢氧燃料电池的性能与质子交换膜的性能密切相关. 在燃料电池运行过程中,反应生成的水和加湿气体所含水的扩散渗透与膜内质子拖拽共同作用实现膜中水的平衡,影响膜的欧姆电阻,进而影响电池性能. 本文通过掺杂Pt/C对质子膜进行改性,并测试了改性膜的交流阻抗、吸水特性等物理性质和单电池性能及高频阻抗,说明由膜中的Pt/C催化剂原位催化渗透到膜中的氢气和氧气反应生成水,改善了电池低湿度运行时膜的含水率,从而降低膜电阻,提升电池性能

References

[1]  Li X G. Principles of fuel cells[M]. CRC Press, 2006.
[2]  Springer T E, Zawadzinski T A, Gottesfeld S. Polymer electrolyte fuel cell model[J]. Journal of The Electrochemical Society, 1991, 138(8): 2234-2342.
[3]  Barbir F, Fomez T. Efficiency and economics of proton exchange membrane (PEM) fuel cells[J]. International Journal of Hydrogen Energy, 1996, 21(10): 891-901.
[4]  Kundu S, Simon L C, Fowler M W. Comparison of two accelerated NafionTM degration experiments[J]. Polymer Degration and Stability, 2008, 93(1): 214-224.
[5]  Belkhiri Z, Zeroual M, Moussa H B, et al. Effect of temperature and water content on the performance of PEM fuel cell[J]. Revue des Energies Renouvelables, 2011, 14(1): 121-130.
[6]  Hiroyuki U, Yoshihiko U, Hiroki H, et al. Self-humidifying electrolyte membranes for fuel cells preparation of highly dispersed TiO2 particles in Nafion 112[J]. Journal of The Electrochemical Society, 2003, 150(1): A57-A62.
[7]  Yi B L(衣宝廉). Fuel cells - principle, technology, application[M]. Beijing: Chemical Industry Press(化学工业出版社), 2003: 1-8.
[8]  Zhang H W(张宏伟), Shen P K(沈培康). Research process of polymer electrolyte membrane for fuel cells[J]. Science China(中国科学:化学), 2012, 42(7): 954-982.
[9]  Peihambardoust S J, Rowshanzamir S, Amjadi M. Review of the proton exchange membranes for fuel cell application[J]. International Journal of Hydrogen Energy, 2010, 35(17): 9349-9384.
[10]  Neburchilov V, Martin J, Wang H. A review of polymer electrolyte membranes for direct methanol fuel cells[J]. Journal of Power Sources, 2007, 38: 169-221.
[11]  Dimitrova P, Friedrich K A, Stimming U, et al. Modified NafionR-based membranes for use in direct methanol fuel cells[J]. Solid state ionic, 2002, 150(1/2): 115-122.
[12]  Ma J X(马建新), Yi B L(衣宝廉), Yu H M(俞红梅), et al. Review on preparation method of membrane electrode assembly for PEMFC [J]. Progress in chemistry(化学进展), 2004, 16(5): 804-812.
[13]  Sun K(孙琨). Preparation and characterization of novel proton exchange membrane based on Nafion[D], 2009.
[14]  Watanabe M, Uchida H, Emori M. Analyses of self-humidification and suppression of gas crossover in Pt-dispersed polymer electrolyte membranes for fuel cells[J]. Journal of The Electrochemical Society, 1998, 14(4): 1137-1141.
[15]  Sahu A K, Pitchumani S, Shukla A K, et al. Nafion and modified-Nafion membranes for polymer electrolyte fuel cells: An overview[J]. Indian Academy of Sciences, 2009, 32(3): 285-294.
[16]  Amjadi M, Rowshanzamir S, Peihambardoust S J. Investigation of physical properties and cell performance of Nafion/TiO2 nanocomposite membranes for high temperature PEM fuel cells[J]. International Journal of Hydrogen Energy, 2010, 35(17): 9252-9260.
[17]  Choi W C, Kim J D, Woo S I. Modification of proton conducting membrane for reducing methanol crossover in a direct-methanol fuel cell[J]. Journal of Power Sources, 2001, 96: 411-414.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133