|
- 2015
液栅型石墨烯场效应管的缓冲液浓度和pH响应特性
|
Abstract:
摘要 本文使用化学气相沉积(Chemical Vapor Deposition,CVD)石墨烯制作了高灵敏度、低噪声的液栅型石墨烯场效应管(Solution-Gated Graphene Field Effect Transistors,SGFETs),并测试了该器件对磷酸盐缓冲液(Phosphate Buffered Saline,PBS)浓度和pH的响应特性. 随缓冲液浓度的增大,SGFETs转移特性曲线的最小电导点向左偏移,偏移量与溶液浓度的自然对数呈线性关系. 随pH的增大,其最小电导点向右偏移,偏移量与溶液pH呈线性关系. 该响应特性对石墨烯生化传感器排除外界影响因素有一定的指导作用
[1] | Zaifuddin N M, Okamoto S, Ikuta T, et al. pH sensor based on chemical-vapor-deposition-synthesized graphene transistor array[J]. Japanese Journal of Applied Physics, 2013, 52(6): 06GK04. |
[2] | Chen F, Qing Q, Xia J L, et al. Electrochemical gate-controlled charge transport in graphene in ionic liquid and aqueous solution[J]. Journal of the American Chemical Society, 2009, 131(29): 9908-9909. |
[3] | Leenaerts O, Partoens B, Peeters F M. Adsorption of H2O, NH3, CO, NO2, and NO on graphene: A first-principles study[J]. Physical Review B: Condensed Matter and Materials Physics, 2008, 77(12): 125416. |
[4] | Schwierz F. Graphene transistors[J]. Nature Nanotechnology, 2010, 5(7): 487-496. |
[5] | Pumera M, Ambrosi A, Bonanni A, et al. Graphene for electrochemical sensing and biosensing[J]. TrAC-Trends In Analytical Chemistry, 2010, 29(9): 954-965. |
[6] | Lee C, Wei X D, Kysar J W, et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene[J]. Science, 2008, 321(5887): 385-388. |
[7] | Sohn I Y, Kim D J, Jung J H, et al. pH sensing characteristics and biosensing application of solution-gated reduced graphene oxide field-effect transistors[J]. Biosensors & Bioelectronics, 2013, 45: 70-76. |
[8] | Park S J, Kwon O S, Lee S H, et al. Ultrasensitive flexible graphene based field-effect transistor (FET)-type bioelectronic nose[J]. Nano Letters, 2012, 12(10): 5082-5090. |
[9] | Ang P K, Chen W, Wee A T S, et al. Solution-gated epitaxial graphene as pH sensor[J]. Journal of the American Chemical Society, 2008, 130(44): 14392-14393. |
[10] | Lei N, Li P F, Xue W, et al. Simple graphene chemiresistors as pH sensors: Fabrication and characterization[J]. Measurement Science & Technology, 2011, 22(10): 107002. |
[11] | Ohno Y, Maehashi K, Yamashiro Y, et al. Electrolyte-gated graphene field-effect transistors for detecting pH protein adsorption[J]. Nano Letters, 2009, 9(9): 3318-3322. |
[12] | Israelachvili J N. Intermolecular and surface forces[M]. Burlington: Academic Press, 2011, 291-337. |
[13] | Chen J H, Jang C, Adam S, et al. Charged-impurity scattering in graphene[J]. Nature Physics, 2008, 4(5): 377-381. |
[14] | Xia J L, Chen F, Li J H, et al. Measurement of the quantum capacitance of graphene[J]. Nature Nanotechnology, 2009, 4(8): 505-509. |
[15] | Stine R, Mulvaney S P, Robinson J T, et al. Fabrication, optimization, and use of graphene field effect sensors[J]. Analytical Chemistry, 2013, 85(2): 509-521. |
[16] | Mohanty N, Berry V. Graphene-based single-bacterium resolution biodevice and DNA transistor: Interfacing graphene derivatives with nanoscale and microscale biocomponents[J]. Nano Letters, 2008, 8(12): 4469-4476. |
[17] | Gautam M, Jayatissa A H. Graphene based field effect transistor for the detection of ammonia[J]. Journal of Applied Physics, 2012, 112(6): 064304. |
[18] | Schedin F, Geim A K, Morozov S V, et al. Detection of individual gas molecules adsorbed on graphene[J]. Nature Materials, 2007, 6(9): 652-655. |
[19] | Lu J P. Elastic properties of carbon nanotubes and nanoropes[J]. Physical Review Letters, 1997, 79(7): 1297-1300. |
[20] | Chen F, Xia J L, Tao N J. Ionic screening of charged-impurity scattering in graphene[J]. Nano Letters, 2009, 9(4): 1621-1625. |