全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
-  2015 

刻蚀剂对IrO2-MnO2阳极纳米涂层表面形貌及电化学行为的影响
Effects of Etchants on Surface Morphologies and Electrochemical Performance of IrO2-MnO2 Anodic Nano-Coatings

DOI: 10.13208/j.electrochem.140516

Keywords: 刻蚀剂,IrO2-MnO2阳极涂层,热分解,循环伏安电荷,电流密度,
etchants
,IrO2-MnO2 coating anode,thermal decomposition,cyclic voltammetric charge,current density

Full-Text   Cite this paper   Add to My Lib

Abstract:

摘要 采用传统热分解法制得了不同刻蚀剂(HCl、H2SO4、C2H2O4和HF)处理的Ti基IrO2-MnO2纳米涂层阳极,使用场发射扫描电子显微镜(FESEM)、循环伏安(CV)及极化技术等观察和研究各纳米涂层阳极表面形貌及其电化学性能. 结果表明,与HCl和C2H2O4刻蚀剂相比,HF和H2SO4刻蚀的基底涂层表面IrO2纳米颗粒更为密集且尺寸更大;H2SO4刻蚀处理的Ti基IrO2-MnO2阳极电催化活性最佳,HF次之,C2H2O4再次之,HCl最差

References

[1]  Li Y J, Chang C C, Wen T C. A mixture design approach to thermally prepared Ir-Pt-Au ternary electrodes for oxygen reduction in alkaline solution[J]. Journal of Applied Electrochemistry, 1997, 27(2): 227
[2]  Hu J M, Meng H M, Zhang J Q, et al. Effect of crystallite orientation of IrO2 rutile on the corrosion characteristics of IrO2+Ta2O5 oxide coatings[J]. Journal of Materials Science Letters, 2001, 20(14): 1353-1355.
[3]  Ye Z G, Meng H M, Sun D B. New degradation mechanism of Ti/IrO2+MnO2 anode for oxygen evolution in 0.5M H2SO4 solution[J]. Electrochimica Acta, 2008, 53(18): 5639-5643.
[4]  Bai S J(白少金), Wei Z P(魏宗平), Wang X(王欣), et al. Preparation and performance of novel IrO2-Ta2O5 coated titanium anode with embedded nanoscale IrO2[J]. Transactions of Nonferrous Metals Society of China(中国有色金属学报), 2011, 21(3): 669-674.
[5]  Fóti G, Mousty C, Reid V, Comninellis C. Characterization of DSA type electrodes prepared by rapid thermal decomposition of the metal precursor[J]. Electrochimica Acta, 1998, 44(5): 813-818.
[6]  Simon P, Gogotsi Y. Materials for electrochemical capacitors[J]. Nature Materials, 2008, 7(11): 845-854.
[7]  Toupin M, Brousse T, Belanger D. Charge storage mechanism of MnO2 electrode used in aqueous electrochemical capacitor[J]. Chemistry of Materials, 2004, 6(16): 3184-3190.
[8]  Yeo R S, Orehotsky J, Visscher W, et al. Ruthenium-based mixed oxides as electrocatalysts for oxygen evolution in acid electrolytes[J]. Journal of Electroanalytical Chemistry, 1981, 128(9): 1900-1904.
[9]  Ye Z G, Meng H M, Chen D, et al. Structure and characteristics of Ti/IrO2(x)+MnO2(1-x) anode for oxygen evolution[J]. Solid State Sciences, 2008, 10(3): 346-354.
[10]  Ye Z G, Meng H M, Sun D B. Electrochemical impedance spectroscopic (EIS) investigation of the oxygen evolution reaction mechanism of Ti/IrO2(x)+MnO2(1-x) electrodes in 0.5M H2SO4 solution[J]. Journal of Electroanalytical Chemistry, 2008, 621(1): 49-54.
[11]  Zhou X L, Ye Z G, Hua X Z, et al. Electrocatalytic activity and stability of Ti/IrO2+MnO2 anode in 0.5 M NaCl solution[J]. Journal of Solid State Electrochemistry, 2010, 14(7): 1213-1219.
[12]  Xu H(徐浩), Yan W(延卫), You L(游莉). Effects of various acids treatment on the properties of titanium substrate[J]. Rare Metal Materials and Engineering(稀有金属材料与工程), 2011, 40(9): 1550-1554.
[13]  Lamolle S F, Monjo M, Rubert M, et al. The effect of hydro?uoric acid treatment of titanium surface on nanostructural and chemical changes and the growth of MC3T3-E1 cells[J]. Biomaterials, 2009, 30(5): 736-742.
[14]  Spinolo G, Ardizzone S, Trasatti S. Surface Characterization of Co3O4 electrodes prepared by the sol-gel method[J]. Journal of Electroanalytical Chemistry, 1997, 423(1): 49-57.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133