|
- 2015
钛基金属氧化物电极制备及其氨氮废水降解性能
|
Abstract:
摘要 采用热分解方法制备了4种电极钛基金属氧化物:Ti/SnO2+Sb2O3、Ti/SnO2+Sb2O3/SnO2+IrO2、Ti/SnO2+Sb2O3/SnO2+RuO2和Ti/SnO2+Sb2O3/SnO2+CeO2. X-射线衍射分析表明Ti/SnO2+Sb2O3/SnO2+CeO2电极的CeO2晶体结构完好,连续工作较长时间电极表面没有明显析氧. 使用该电极电解氧化氨氮模拟废水(降解2 h),氨氮模拟废水从高浓度(500 mg·L-1)降解为较低浓度(180 mg·L-1),降解效率可达64%,电解活性最佳
[1] | Van Hege K, Verhaege M, Verstraete W. Electro-oxidative abatement of low-salinity reverse osmosis membrane concentrates[J]. Water Research, 2004, 38(6): 1550-1558. |
[2] | Moraes P B, Bertazzoli R. Electrodegradation of landfill leachate in a flow electrochemical reactor[J]. Chemosphere, 2005, 58(1): 41-46. |
[3] | Zhou L, Cheng Y F, Amerein M. Fabrication by electrolytic deposition of platinum black electrocatalyst for oxidation of ammonia in alkaline solution[J]. Journal of Power Sources, 2008, 177(1): 50-55. |
[4] | Bernet N, Delgenes N. Combined anaerobic SBR for the treatment of piggery wastewater[J]. Water Research, 2003, 34(2): 611-619. |
[5] | Chiang L C, Chang J E, Wen T C. Indirect oxidation effect in electrochemical oxidation treatment of landfill leachate[J].Water Research, 1995, 29(2): 671-678. |
[6] | Wang X(王欣), Tang D(唐电), Zhou J N(周敬恩). Effect of RuO2 on the microstructure, morphology and solid phase of RuO2+SnO2+TiO2/Ti anode[J]. Journal of The Chinese Ceramic Society(中国陶瓷科学), 2002, 30(1): 49-52. |
[7] | Lin H B(林海波), Fei J M(费建民), Zhang H B(张恒彬). Investigation on electrocatalytic oxidation treatment of the effluent wastewater in a fertilizer plant[J]. Industry Water Treament(工业废水处理), 2004, 24(4): 36-38. |
[8] | Charng G J, Ju S H, Hsieh K C. Performance evaluation of single-sludge reactor system high strength nitrogen wastewater[J]. Journal of Hazardous Materials, 2001, 85(3): 213-227. |
[9] | Janssen J J, Koene L. The role of electrochemistry and electrochemical technology in environmental protection[J]. Chemical Engineering Journal, 2002, 85(2/3): 137-146. |
[10] | Wang Z X(王兆熊), Guo C T(郭崇涛),Zhang Y(张英), et al. Chemical environment protection and “three wastes” treatment technology[M]. Beijing: Chemical Industry Press(化学工业出社), 1982: 212 |
[11] | Huang H M(黄海明), Xiao X M(肖贤明), Yan B(晏波). Expermental research on the treatment of low concentration ammonia nitrogen wastewater by breakpoint chlorination[J]. Technology of Water Treatment(水处理技术), 2008, 34(8): 63-66. |
[12] | Hou J Y(侯峰岩), Wang W(王为). Electrochemical technology and environmental protection[J]. Chemical Industry and Engineering Progress(化学工业与能源进展), 2003, 22(5): 471-476. |
[13] | Zhang H, Li Y L, Wu X G, et al. Application of response surface methodology to the treatment landfill leachate in a three-dimensional electrochemical reactor[J]. Waste Management, 2010, 30(11): 2096-2102. |
[14] | Kim S, Choi W. Visible-light-induced photocatalytic degradation of 4-chlorophenol and phenolic compounds in aqueous suspension of pure titania: Demonstrating the existence of a surface-complex-mediated path[J]. The Journal of Physical Chemistry C, 2005, 109(11): 5143 -5149. |
[15] | Martinez-Huitle C A, Ferro S. Electrochemical oxidation of organic pollutants for the wastewater treatment: Direct and indirect processes[J]. Chemical Society Reviews, 2006, 35(12): 1324-1340. |
[16] | Koren D W, Gould W D. Biological remove of ammonia and nitrate from simulated mine and mill efflunets[J]. Hydrometallurgy, 2000, 56(2): 127-144. |